Sevenfold enhancement on porphyrin dye efficiency by coordination of ruthenium polypyridine complexes.

نویسندگان

  • André L A Parussulo
  • Bernardo A Iglesias
  • Henrique E Toma
  • Koiti Araki
چکیده

Sevenfold enhancement of photoconversion efficiency was achieved by incorporation of peripheral ruthenium complexes to a porphyrin dye, generating supramolecular effects capable of playing several key roles (e.g., transferring energy to, inhibiting aggregation, and accepting the hole generated in the porphyrin center after electron injection), providing new insights for the design of better DSSC photosensitizers.

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عنوان ژورنال:
  • Chemical communications

دوره 48 55  شماره 

صفحات  -

تاریخ انتشار 2012